邓清海
发布人:吴波  发布时间:2017-04-24   浏览次数:213




邓清海(DENG Qing-Hai) 教授:上海市东方学者。2003年于武汉大学化学与分子科学学院获理学学士学位;2009年于中国科学院上海有机化学研究所获理学博士学位,师从支志明院士(香港大学);2010-2012年获德国洪堡基金会资助于德国海德堡大学从事博士后研究;2012-2014年获海德堡大学和巴斯夫公司资助于海德堡催化研究实验室从事博士后研究;2015年加入上海师范大学。

Email: qinghaideng@shnu.edu.cn

  

1.研究方向:

1. 新型配体的设计、合成及应用;

2. 不对称催化;

3. 金属催化的C-N键形成反应

  

2.发表文章和专利:

1.Q.-H. DengR. L. Melen, L. H. Gade*.Anionic Chiral Tridentate N-Donor Pincer Ligands in Asymmetric Catalysis. Acc. Chem. Res. 2014, 47, 3162.

2.Q.-H. DengRettenmeier, C., H. Wadepohl, L. H. Gade*.Copper-Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic TrifluoromethylthiolationsChem. Eur. J. 2014, 20, 93.(Highlighted by “Synfacts 2014, 398.”)

3.Q.-H. Deng, T. Bleith, H. Wadepohl, L. H. Gade*. Enantioselective Iron-Catalyzed Azidation of β-Ketoesters and Oxindoles. J. Am. Chem. Soc. 2013, 135, 5356.

4.Q.-H. Deng, H. Wadepohl, L. H. Gade*. Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters. J. Am. Chem. Soc. 2012134, 10769. (Highlighted by “Synfacts 2012, 979.”)

5.Q.-H. DengH. Wadepohl, L. H. Gade*. Highly Enantioselective Copper-Catalyzed Alkylation ofβ-Ketoesters and Subsequent Cyclization to Spirolactones/Bi-spirolactones. J. Am. Chem. Soc. 2012,134, 2946. (Highlighted by “Synfacts 2012, 512.”)

6.Q.-H. Deng, H. Wadepohl, L. H. Gade*. The Synthesis of a New Class of Chiral Pincer Ligands and Their Applications in Enantioselective Catalytic Fluorinations and the Nozaki-Hiyama-Kishi Reaction. Chem. Eur. J. 2011, 17, 14922.

7.J.-C. Wang, Z.-J. Xu, Z. Guo, Q.-H. Deng, C.-Y. Zhou, X.-L. Wan, C.-M. Che*. Highly Enantioselective Intermolecular Carbene Insertion to C–H and Si–H Bonds Catalyzed by a Chiral Iridium(III) Complex of a D4-symmetric Halterman Porphyrin Ligand. Chem. Commun. 2012, 48, 4299.

8.Q.-H. Deng, J.-C. Wang, Z.-J. Xu, C.-Y. Zhou, C.-M. Che*Metal-Free Intramolecular Aziridination of Allylic Carbamates Mediated by Hypervalent Iodine Compounds. Synthesis, 2011, 18, 2959.

9.Q.-H. Deng, J. Chen, J.-S. Huang, S. S.-Y. Chui, N. Zhu, G.-Y. Li, C.-M. Che*. Trapping Reactive Metal-Carbene Complexes by a Bis-Pocket Porphyrin: X-ray Crystal Structures of Ru=CHCO2Et and trans-[Ru(CHR)(CO)] Species and Highly Selective Carbenoid Transfer Reactions. Chem. Eur. J. 2009, 15, 10707.

10.Q.-H. Deng, H.-W. Xu, A. W.-H. Yuen, Z.-J. Xu, C.-M. Che*. Ruthenium-Catalyzed One-Pot Carbenoid N-H Insertion Reactions and Diastereoselective Synthesis of Prolines. Org. Lett. 2008, 10, 1529.(Highlighted by “Synfacts 2008, 730.” and “Stereoselective C-N Ring Construction, D. F. Taber,Org. Chem. Highlights 2008, November 17.)

11.H.-Y. Thu, G. S.-M. Tong, J.-S. Huang, S. L.-F. Chan, Q.-H. Deng, C.-M. Che*. Highly Selective Metal Catalysts for Intermolecular Carbenoid Insertion into Primary C-H Bonds and Enantioselective C-C Bond Formation.Angew. Chem. Int. Ed. 2008, 47, 9747.(Inside Cover” paper)

12.M. K.-W. Choi, W.-Y. Yu, M.-H. So, C.-Y. Zhou, Q.-H. Deng, C.-M. Che*. A Non-Cross-Linked Soluble Polystyrene-Supported Ruthenium Catalyst for Carbenoid Transfer Reactions.Chem. Asian J. 2008, 3, 1256.

13.J.-P. Zhou, L.-N. Zhang*, Q.-H. Deng, X.-J. Wu.Synthesis and Characterization of Cellulose Derivatives Prepared in NaOH/Urea Aqueous Solutions.J. Polym. Sci., Part A: Polym. Chem, 200442, 5911.

14.周金平张俐娜邓清海中国专利No. ZL03128387.X, 2005. 7.羟丙基纤维素的制备方法。