刘国华
发布人:吴波  发布时间:2017-04-24   浏览次数:268

1. 个人简介:

刘国华 博士,教授,有机化学专业硕士生导师中国科学院化学研究所博士,荷兰格罗宁根大学化学系博士后现为上海师范大学生命与环境科学学院化学系有机化学硕士点负责人;资源化学教育部联合合作实验室副主任;担任上海市化学化工学会有机化学专业委员会理事,国际期刊Scientific Reports编委和上海市师范大学学报自然科学版编委。

2. 主要研究方向:

[1] 负载型催化剂的制备

[2] 不对称催化

[3] 金属有机化学

3. 代表性科研项目:

[1] 催化活性点分离的双功能负载型催化剂的构建和串联不对称反应研究,国家自然科学基金(面上项目)2017-2020

[2] 手性功能化的有机/无机杂化纳米材料制备及其合成反应评价,上海市科学技术委员会科研项目,2012-2015

[3]介孔结构的硅基载体和限域效应对不对称氢化反应影响,上海市教育委员会重点科研项目2012-2014

[4]手性双功能介孔功能材料与金属配位方式的探讨及不对称氢化反应研究,上海市科学技术委员会基础研重点项目2010-2013

[5] 手性双功能介孔功能材料与金属配位方式的探讨及不对称氢化反应研究,上海市科学技术委员会基础研究重大项目子项目2010-2013

4. 代表性论文:

  1. Liang Wu, Ronghua Jin, Liang Li, Xiaoying Hu, Tanyu Cheng, and Guohua Liu,* A Michael Addition−Asymmetric Transfer Hydrogenation One-Pot Enantioselective Tandem Process for Syntheses of Chiral γ Secondary Amino Alcohols, Org. Lett.2017, 19), 3047–3050. (Highlighted in Synfacts 2017, 13, 0904).

  2. Dongsong Zheng,   Qiankun Zhao,   Xiaoying Hu,   Tanyu Cheng,   Guohua Liu*  and   Wei Wang*   A dynamic kinetic asymmetric transfer hydrogenation–cyclization tandem reaction: an easy access to chiral 3,4-dihydro-2H-pyran-carbonitriles, Chem. Commun.2017,53, 6113-6116. (Highlighted in Synfacts 2017, 13(09), 0918).

  3. Xuelin Xia, Jingjing Meng, Hanxin Wu, Tanyu Cheng and Guohua Liu*, Integration of multiple active sites on large-pore mesoporous silica for enantioselective tandem reactions, Chem. Commun. 2017, 53, 1638—1641.

  4. Jianyou Xu, Tanyu Cheng, Kun Zhang, Ziyun Wang and Guohua Liu*, Enantioselective tandem reaction over a site-isolated bifunctional catalyst,Chem. Commun.2016, 52, 6005—6008.

  5. Lingyu Kong,Junwei Zhao, Tanyu Cheng, Jingrong Lin, and Guohua Liu,* A Polymer-Coated Rhodium/Diamine-Functionalized Silica for Controllable Reaction Switching in Enantioselective Tandem Reduction-Lactonization of Ethyl 2-Acylarylcarboxylates,ACS Catal.2016, 6, 2244-2249.

  6. Kun Zhang, Juzeng An, Yanchao Su, Jueyu Zhang, Ziyun Wang, Tanyu Cheng, Guohua Liu*, Amphiphilic Hyperbranched Polyethoxysiloxane: A Self-Templating Assembled Platform to Fabricate Functionalized Mesostructured Silicas for Aqueous Enantioselective Reactions, ACS Catal. 2016, 6, 6229–6235.

  7. Feng Zhou, Xiaoying Hu, Ming Gao, Tanyu Cheng*,Guohua Liu*, An Imidazolium-Modified Chiral Rhodium/diamine-Functionalized Periodic Mesoporous Organosilica for Asymmetric Transfer Hydrogenation of a–Haloketones and Benzils in Aqueous Medium,Green Chem.2016, 18, 5651-5657.

  8. Xuelin Xia, Meng Wu, Ronghua Jin, Tanyu Cheng and Guohua Liu,* One-pot Relay Reduction-Isomerization of ß-Trifluoromethylated-a,ß-Unsaturated Ketones to chiral ß-Trifluoromethylated Saturated Ketones Over Combined Catalysts in Aqueous Medium, Green Chem.2015, 17, 3916 – 3922.

  9. Dacheng Zhang Tanyu Cheng Guohua Liu*, An imidazolium-based organopalladium-functionalized organic–inorganic hybrid silica promotes one-pot tandem Suzuki cross coupling–reduction of haloacetophenones and arylboronic acids, Applied Catalysis B: Environmental, 2015, 174–175, 344–349.

  10. Tanyu Cheng, Qiankun Zhao, Dacheng Zhang and Guohua Liu*, Transition-metal-functionalized ordered mesoporous silicas: an overview of sustainable chiral catalysts for enantioselective transformations, Green Chem.2015, 17, 2100 (invited review paper).

5. 表性授权专利:

  1. 刘国华,徐建友,熊锡,吴亮,金荣华,程探宇;一种蛋壳结构的钯钌双金属功能化的介孔纳米催化剂及其制备方法, 专利号:ZL 2015 1 0345863.7.  

  2. 刘国华,张大诚,王凯雯,吕雯雯,顾坤鹏,程探宇;一种Ru-Pd双金属负载型手性催化剂及其制备工艺,专利号:ZL 2014 1 0174583.X

  3. 刘国华,张大诚,徐建友,赵乾坤,吴猛,王金玉;一种具有相转移催化性能的咪唑鎓盐型卡宾钯催化剂及其制备方法,专利号:ZL 2014 1 0081268.2

  4. 刘国华,高小双,徐向明,金荣华,程探宇;一种有序介孔有机硅磁球Fe3O4@PMO材料的制备方法,专利号:ZL 2013 1 0176009.3 (授权日期:2016-05-13)

  5. 刘国华,邓博心,肖伟,程探宇; 一种咪唑功能化的两亲介孔有机硅材料的制备方法,专利号:ZL 2013 1 0285620.X.


更新时间:2017年11月