赵宝国
发布人:吴波  发布时间:2017-11-10   浏览次数:24

1. 个人简介:

赵宝国博士,教授,有机化学专业,硕士生导师Email: zhaobg2006@shnu.edu.cn


教育经历:

2003-2006,博士,中国科学院上海有机化学研究所

1999-2002,硕士,南京大学

1992-1996学士,武汉大学

工作经历:

2006-2011美国科罗拉多州立大学博士后

2011-至今,上海师范大学 教授


2. 主要研究方向:

[1] 新型有机反应的发展

[2] 不对称催化

[3] 天然产物全合成


3. 代表性科研项目:

[1] 手性吡哆醛/吡哆胺催化剂的发展及其仿生催化α-酮酸的不对称转氨化研究,国家自然科学基金(面上项目),2017-2020

[2] Aminative Umpolung的策略由醛合成高烯丙基胺的研究,国家自然科学基金(面上项目),2015-2018

[3] 过渡金属催化的硫代酰胺与卤代物及其类似物的偶联反应的研究、发展和应用,国家自然科学基金(面上项目),2013-2014


4. 代表性论文著作:

[1] Feng Liu, JiaxinTian, Yong Liu, Chuangan Tao, Hao Zhu, Aina Zhang, Dongfang Xu and Baoguo Zhao*“DecarboxylativeUmpolung of Conjugated Enal to β-Carbanion for Intramolecular Nucleophilic Addition to Aldehyde”Org. Chem. Fron.2017,4,1586.

[2]Xiaoyu Lan, Chuangan Tao, Xuliang Liu, Aina Zhang, Baoguo Zhao*“Asymmetric Transamination of α-Keto Acids Catalyzed by Chiral Pyridoxamines”Org. Lett. 2016, 18, 3658.

[3]Yong Ethan Liu, Zhaole Lu, Bo Li, Jiaxin Tian, Feng Liu, Junyu Zhao, Chengkang Hou, Yingkun Li,Lili Niu, Baoguo Zhao* “Enzyme-Inspired Axially Chiral Pyridoxamines Armed with a Cooperative Lateral Amine Chain for Enantioselective Biomimetic Transamination”J. Am. Chem. Soc.2016, 138, 10730.

[4]Limin Shi, Chuangan Tao, Qin Yang, Yong Ethan Liu, Jing Chen, Jianfeng Chen, Jiaxin Tian, Feng Liu, Bo Li, Yongling Du, Baoguo Zhao* “Chiral Pyridoxal-Catalyzed Asymmetric Biomimetic Transamination of α-Keto Acids” Org. Lett.2015,17, 5784.

[5]Juan Xu,Jing Chen,Lei Ding, Xuliang Liu, Dongfang Xu, Baoguo Zhao*Synthesis of α-Methylene-γ-amino acid Esters from Aldehydes via Aminative Umpolung StrategyAdv. Synth. Catal. 2014, 356, 3219.

[6]Xuliang Liu, Ang Gao, Lei Ding,Juan Xu,Dongfang Xu, Baoguo Zhao*Aminative Umpolung Synthesis of Vicinal Amines from Aromatic Aldehydes”Org. Lett. 2014, 16, 2118.

[7]Lei Ding, Jing Chen, Yifan Hu, Juan Xu, Xing Gong, Dongfang Xu, Baoguo Zhao*, Hexing Li “Aminative Umpolung of Aldehydes to α-Amimo Anion Equivalents for Pd-catalyzed Allyation: An Efficient Synthesis of Homoallylic Amines” Org. Lett.2014, 16, 720.

[8]Baoguo Zhao, Zhaobin Han, Kuiling Ding* N-H Functions in Organometallic Catalysis”Angew. Chem. Int. Ed.2013, 52, 4744.

[9]Richard G. Cornwall, Baoguo Zhao, Yian Shi* Catalytic Asymmetric Synthesis of Cyclic Sulfamides from Conjugated Dienes Org. Lett.2013, 15, 796.

[10]Yingguang Zhu, Baoguo Zhao, Yian Shi* Highly Efficient Cu(I)-Catalyzed Oxidation of Alcohols to Ketones and Aldehydes with DiaziridinoneOrg. Lett.2013, 15, 992.

[11]Baoguo Zhao, Xingao Peng, Yingguang Zhu, Thamos A. Ramirez, Richard G. Cornwall, Yian Shi* “Cu(I)-Catalyzed Diamination of Conjugated Dienes. Complementary Regioselectivity from Two Distinct Mechanistic Pathways” J. Am. Chem. Soc.2011, 133, 20890-20900.

[12]Baoguo Zhao, Xingao Peng, Sunliang Cui, Yian Shi* “Cu(I)-catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways” J. Am. Chem. Soc.2010, 132, 11009-11011.

[13]Baoguo Zhao, Haifeng Du, Sunliang Cui, Yian Shi* “Synthetic and Mechanistic Studies of Pd(0)-Catalyzed Diamination of Conjugated Dienes” J. Am. Chem. Soc.2010, 132, 3523-3532.

[14]Baoguo Zhao, Haifeng Du, Yian Shi*“A Cu(I)-Catalyzed C-H α-Amination of Esters. Direct Synthesis of Hydantoins”J. Am. Chem. Soc.2008, 130, 7220-7221.


5. 获奖情况:

[1] 入选上海市东方学者特聘教授,2010年。

[2] 入选教育部“新世纪优秀人才计划”,2012年。

[3] 入选上海市“浦江人才计划”,2012年。


更新时间:2017年11月